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By default the Profile container will not get attached if a local profile for that user exists. That is of course, unless you’ve enabled the “Delete local profile…”. That should delete the local profile first (assuming it’s not locked) then attach the Profile Container. I’d double check in the registry that that setting is enabled (1) and look in the Profile log for more information.

IME I've found the "delete local profile when VHD should apply" a bit problematic. Like Nathan said, check that it's not in use by something