IF I remember correctly, PVS Accelerator caches bits of the PVS VHD in the hosts memory/storage requiring less reaches out to the PVS servers to stream those bits. This of course accelerates the bootup process as well as running applications. As a lot of Login processes are dependent on network connectivity to the domain controllers for authentication, GPOs, Login scripts, etc, and network connectivity to shared file servers, print servers, etc. I'm not sure how much acceleration you'll see around login times specfically.