My understanding is that this is related to the segment level query results cache ... which stores segment level results for a specific query.
segmentAndCache/time includes segments that are found in the results cache and therefore the results can be retrieved and returned more quickly without having to process the segment ... segment/time does not include cached segment results.
The difference between the two should tell you how effective your segment level results caching is.
Note -- this is not related the handling of segment file data in the Linux file system page cache ... that happens regardless of whether segment-level results caching is used or not.